To carry out an alignment of a cross-over filter only through the acoustic frequency response is possible but it is quite difficult, it should be integrated with an impedance measurement and above all with the electrical response measurement across the loudspeaker.
I always measure the response of each individual speaker without a filter when they are already mounted in a loudspeaker, then I identify the optimal cut-off frequencies based on the characteristics of the speakers and also on their response in the room. Then, with the aid of a simulation software, I check the components necessary to make the filter cells and the simulated response of all the ways. I carry out the cross-over and this time I trace the electrical response curves of the crossover to check the cutoff frequencies and also the impedance curve, then I carry out the acoustic response measurement to understand if the simulated project is confirmed.
Normally, the measurement of the real frequency response always differs from the simulated one, therefore it is necessary to make adjustments by tracing and changing the values of the components.
The filter that I have seen in the figure has some values of the components that leave me perplexed, especially the inductances in series with the speakers have an excessive resistive value and cause a strong attenuation.